An analysis of radiation effects on unsteady MHD free convection flow past a vertical porous plate with thermal diffusion and chemical reaction have been discussed. The dimensionless governing equations are linear and coupled. These equations are solved analytically by using perturbation technique. The expressions for velocity, temperature and concentration are obtained and discussed their variations under several parameters through graphs. The skin-friction, rate of heat transfer in the form of Nusselt number and the rate of mass transfer in the form of Sherwood number are also derived and discussed through tables.