It was therefore though worthwhile to synthesize and characterize some neutral mixed lignad cyanbo nitrosyl (Cr NO)5 complexes of chromium and Fe(NO)6 with some monodentate aromatic amines like 4-amino cumenes; 2-methyl-5-isopopyl amine, 4-tertiary butyl aniline and 2,4,6-trimethoxy aniline and bidentte aromatic amine like 3-cyano aniline. The complexes this synthesized would require an attention of reactivities, which can be dealt using different physico-chemicals techniques. Thus a correlation can be made on the changes notice with the help of existing theories in band.